If you want to play a perfect B chord then you have to practice and practice. First get your index finger used to making that barre shape, so every string sounds perfect when you have it layed across the neck. For the other part I just kinda bend my ring finger over the right strings. If you want a nice open B you can play 024400 (low-high) and it is very close to a normal B but nice and open. This chord sounds good when played in E with other chords like E, A2, C#m, and F#m.
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